SURFACE-WATER-DISCHARGE AND SURFACE-WATER-QUALITY RECORDS

Remark Codes

The following remark codes may appear with the water-quality data in this section:
PRINT OUTPUT        REMARK
     E              Estimated value.

     >              Actual value is known to be 
                    greater than the value shown.

     <              Actual value is known to be 
                    less than the value shown.

     K              Results based on colony
                    count outside the acceptance
                    range (non-ideal colony count).

Water-Quality-Control Data

Data generated from quality-control (QC) samples are a requisite for evaluating the quality of the sampling and processing techniques as well as data from the actual samples themselves. Without QC data, environmental sample data cannot be adequately interpreted because the errors associated with the sample data are unknown. The various types of QC samples collected by this District are described in the following section. Procedures have been established for the storage of water-quality-control data within the USGS. These procedures allow for storage of all derived QC data and are identified so that they can be related to corresponding environmental samples.

The dates and times of QC samples are noted in the water quality tables, but the QA data are not displayed. The various types of QA data are available upon request from the U.S. Geological Survey North Dakota District office (see address on back of the title page of this report).

Blank Samples

Blank samples are collected and analyzed to ensure that environmental samples have not been contaminated by the overall data-collection process. The blank solution used to develop specific types of blank samples is a solution that is free of the analytes of interest. Any measured value signal in a blank sample for an analyte (a specific component measured in a chemical analysis) that was absent in the blank solution is believed to be due to contamination. There are many types of blank samples possible, each designed to segregate a different part of the overall data-collection process. The types of blank samples collect in this District are:

Field blank - a blank solution that is subjected to all aspects of sample collection, field processing preservation, transportation, and laboratory handling as an environmental sample.

Trip blank - a blank solution that is put in the same type of bottle used for an environmental sample and kept with the set of sample bottles before and after sample collection.

Equipment blank - a blank solution that is processed through all equipment used for collecting and processing an environmental sample (similar to a field blank but normally done in the more controlled conditions of the office).

Sampler blank - a blank solution that is poured or pumped through the same field sampler used for collecting an environmental sample.

Filter blank - a blank solution that is filtered in the same manner and through the same filter apparatus used for an environmental sample.

Splitter blank - a blank solution that is mixed and separated using a field splitter in the same manner and through the same apparatus used for an environmental sample.

Preservation blank - a blank solution that is treated with the sampler preservatives used for an environmental sample.

Reference Samples

Reference material is a solution or material prepared by a laboratory whose composition is certified for one or more properties so that it can be used to assess a measurement method. Samples of reference material are submitted for analysis to ensure that an analytical method is accurate for the known properties of the reference material. Generally, the selected reference material properties are similar to the environmental sample properties.

Replicate Samples

Replicate samples are a set of environmental samples collected in a manner such that the samples are thought to be essentially identical in composition. Replicate is the general case for which a duplicate is the special case consisting of two samples. Replicate samples are collected and analyzed to establish the amount of variability in the data contributed by some part of the collection and analytical process. There are many types of replicate samples possible, each of which may yield slightly different results in a dynamic hydrologic setting, such as a flowing stream. The types of replicate samples collected in this District are: Sequential samples - a type of replicate sample in which the samples are collected one after the other, typically over a short time.

Split sample - a type of replicate sample in which a sample is split into subsamples contemporaneous in time and space.

Spike Samples

Spike samples are samples to which known quantities of a solution with one or more well-established analyte concentrations have been added. These samples are analyzed to determine the extent of matrix interference or degradation on the analyte concentration during sample processing and analysis.

Dissolved Trace-Element Concentrations

*NOTE.-- Traditionally, dissolved trace-element concen-trations have been reported at the microgram per liter (μg/L) level. Recent evidence, mostly from large rivers, indicates that actual dissolved-phase concentrations for a number of trace elements are within the range of 10's to 100's of nanograms per liter (ng/L). Data above the μg/L level should be viewed with caution. Such data may actually represent elevated environmental concentrations from natural or human causes; however, these data could reflect contamination introduced during sampling, processing, or analysis. To confidently produce dissolved trace-element data with insignificant contamination, the U.S. Geological Survey began using new trace-element protocols at some stations in water year 1994.

Change in National Trends Network Procedures

*NOTE.-- Sample handling procedures at all National Trends Network stations were changed substantially on January 11, 1994, in order to reduce contamination from the sample shipping container. The data for samples before and after that date are different and not directly comparable. A tabular summary of the differences based on a special intercomparison study, is available from the NADP/NTN Coordination Office, Colorado State University, Fort Collins, CO 80523 (Telephone: 303-491-5643).



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